AA and 18650 batteries are both cylindrical, leading some to wonder if they can be used interchangeably. However, they differ in size, chemistry, voltage, capacity, and charging/discharging characteristics.
18650 batteries are slightly larger than AA alkaline batteries and have roughly twice the standard voltage. Additionally, 18650 batteries are more expensive than AA batteries.
What is an 18650 Battery?
The 18650 battery measures approximately 18 x 65 mm, making it slightly larger than an AA battery. It has a nominal voltage of 3.2 to 3.7 volts and a capacity of 1800 to 3500mAh.
An 18650 battery typically requires a Battery Management System (BMS) to prevent overcharging and over-discharging. Additionally, the anode shape varies—some have a flat tip, while others have a protruding tip.
This battery has no memory effect, allowing it to be charged and used at any time without requiring a full charge.

What is an AA Battery?
AA batteries are smaller than 18650 batteries, measuring about 14 x 50 mm. Standard AA batteries have a nominal voltage of 1.5 volts and a capacity between 1800 and 2700mAh.
The chemistry differs between rechargeable and non-rechargeable AA batteries. While rechargeable versions exist, such as Li-ion, NiMH, and NiCd AAs, most commonly referenced AA batteries are non-rechargeable.
Advantages of 18650 battery
It has the advantages of light weight, large capacity, and no memory effect, so it has been widely used. The energy density of lithium-ion batteries is very high. Its capacity is 1.5 to 2 times that of nickel-metal hydride batteries of the same weight, with very low self-discharge. Additionally, lithium-ion batteries have almost no "memory effect" and contain no toxic substances, making them widely used.
1. Large Capacity: The capacity of 18650 lithium batteries typically ranges from 1200mAh to 3600mAh, whereas standard batteries offer around 800mAh. When combined into a battery pack, the capacity can easily exceed 5000mAh.
2. Long Lifespan: The 18650 LiFePO4 battery has a cycle life of over 500 charges under normal use, more than double that of regular batteries.
3. High Safety Performance: The 18650 battery separates the positive and negative electrodes to minimize short circuits. A protection board can be added to prevent overcharging and over-discharging, further extending battery life.
4. High Voltage: The voltage of 18650 batteries is generally 3.6V, 3.8V, or 4.2V, significantly higher than the 1.2V of NiCd and NiMH batteries.
5. No Memory Effect: There is no need to fully discharge before recharging, making usage more convenient.
6. Low Internal Resistance: High-performance 18650 batteries have an internal resistance of around 12 milliohms, with typical values ranging from 13 to 15 milliohms. Performance declines as resistance increases beyond 50 milliohms, and batteries become unusable above 200 milliohms unless used in parallel.
7. Flexible Configuration: 18650 batteries can be arranged in series or parallel to form battery packs.
18650 Lithium Battery Applications
- Energy Storage: Used in base station power supply, clean energy storage, grid power storage, and home solar storage systems.
- Power Applications: Includes electric vehicles, electric bicycles, and new energy vehicles.
- Digital Devices: Found in mobile phones, tablets, laptops, electric toys, MP3/MP4 players, headphones, power banks, model airplanes, and mobile power supplies.
Difference between 18650 battery vs AA battery?
Dimension
Just from the appearance, 18650 battery and AA battery have obvious size difference. The 18650 lithium battery has a diameter of 18mm and a length of 65mm. In comparison, AA batteries (Also known as 14500 batteries) are 14mm in diameter and 50mm in length. Therefore, the size and diameter of 18650 batteries are much larger than AA batteries.
Chemistry
The 18650 battery is a specific-sized rechargeable lithium-ion battery, typically made from lithium iron phosphate (LiFePO4) or NiCoMn ternary material. AA batteries, however, come in various chemistries, including alkaline, zinc-carbon, nickel-cadmium (NiCd), nickel-metal hydride (NiMH), and lithium-ion.
Voltage
18650 batteries have a nominal voltage of 3.7V, whereas AA batteries operate at 1.5V, making their voltage levels significantly different.
Capacity
18650 batteries typically have a capacity of 1800–3500mAh. AA lithium-ion batteries range from 1700–2700mAh, while alkaline AA batteries range from 600–2700mAh.
Performance
With a higher capacity, 18650 batteries store more energy and last longer per charge. In contrast, AA batteries have lower capacity, are often non-rechargeable, and are meant for single use.
Lifespan
AA alkaline batteries are disposable and cannot be recharged. In comparison, 18650 batteries support 800–1000 charge/discharge cycles.
Can We Replace AA Batteries with 18650 Batteries?
No, 18650 batteries cannot replace AA batteries due to their significantly different voltages. AA batteries operate at 1.5V, while 18650 batteries have a nominal voltage of 3.7V. However, 18650 batteries can be used interchangeably with 21700 batteries, as both are rechargeable Li-ion cells with similar voltage.